пятница, 19 апреля 2024 г.

Natural disasters

 

Natural disasters

Natural disasters are large-scale geological or meteorological events that have the potential to cause loss of life or property. These types of disasters include: tornadoes and severe storms, hurricanes and tropical storms, floods, wildfires, earthquakes, drought, avalanche, heat wave, landslide, tsunami, volcanic activity.

 Natural disaster, any calamitous occurrence generated by the effects of natural, rather than human-driven, phenomena that produces great loss of human life or destruction of the natural environment, private property, or public infrastructure. A natural disaster may be caused by weather and climate events or by earthquakeslandslides, and other occurrences that originate at Earth’s surface or within the planet itself. No spot on Earth is immune from a natural disaster; however, certain types of disasters are often limited to or occur more frequently in specific geographic regions.

In modern times, the divide between natural, human-made and human-accelerated disasters is quite difficult to draw. Human choices and activities like architecture, fire, resource management and climate change potentially play a role in causing natural disasters. A natural disaster is the highly harmful impact on a society or community following a natural hazard event. The term "disaster" itself is defined as follows: "Disasters are serious disruptions to the functioning of a community that exceed its capacity to cope using its own resources". Disasters can be caused by natural, man-made and technological hazards, as well as various factors that influence the exposure and vulnerability of a community. A natural disaster is the negative impact following an actual occurrence of natural hazard in the event that it significantly harms a community. An example of the distinction between a natural hazard and a disaster is that an earthquake is the hazard which caused the 1906 San Francisco earthquake disaster. A natural hazard is a natural phenomenon that might have a negative effect on humans and other animals, or the environment. Natural hazard events can be classified into two broad categories: geophysical and biological. Natural hazards can be provoked or affected by anthropogenic processes, e.g. land-use change, drainage and construction.

There are 18 natural hazards included in the National Risk Index of FEMA: avalanche, coastal flooding, cold wave, drought, earthquake, hail, heat wave, tropical cyclone, ice storm, landslide, lightning, riverine flooding, strong wind, tornado, tsunami, volcanic activity, wildfire, winter weather. In addition there are also tornados and dust storms. A natural disaster may cause loss of life, injury or other health impacts, property damage, loss of livelihoods and services, social and economic disruption, or environmental damage.

вторник, 2 апреля 2024 г.

What Is Electrochemistry?

 Electrochemistry is the subdiscipline of Chemistry that deals with the study of the relationship between electrical energy and chemical changes. Chemical reactions that involve the input or generation of electric currents are called electrochemical reactions. Such reactions are broadly classified into two categories:

Download Complete Chapter Notes of Electrochemistry

  1. Production of chemical change by electrical energy, i.e., the phenomenon of electrolysis
  2. Conversion of chemical energy into electrical energy, i.e., the generation of electricity by spontaneous redox reactions.

Electricity can be produced when electrons move from one element to another in certain types of reactions (such as redox reactions). Typically, electrochemistry deals with the overall reactions when multiple redox reactions occur simultaneously, connected via some external electric current and a suitable electrolyte. In other words, electrochemistry is also concerned with chemical phenomena that involve charge separation (as seen commonly in liquids such as solutions). The dissociation of charge often involves charge transfer that occurs homogeneously or heterogeneously between different chemical species.

Electrochemical Cell

A spontaneous chemical process is one which can take place on its own, and in such a process, the Gibbs free energy of a system decreases. In electrochemistry, spontaneous reaction (redox reaction) results in the conversion of chemical energy into electrical energy. The reverse process is also possible where a non-spontaneous chemical reaction occurs by supplying electricity. These interconversions are carried out in equipment called an electrochemical cell.

Types of Electrochemical Cell

Electrochemical cells are of two types: galvanic cells and electrolytic cells

Galvanic Cell

The galvanic cell converts chemical energy into electrical energy, i.e., electricity can be obtained with the help of a redox reaction. The oxidation and reduction take place in two separate compartments. Each compartment consists of an electrolyte solution and a metallic conductor, which acts as an electrode. The compartment containing the electrode and the solution of the electrolyte is called half cells.

четверг, 21 марта 2024 г.

Chemistry Is Everywhere

 Everything you hear, see, smell, taste, and touch involves chemistry and chemicals (matter). And hearing, seeing, tasting, and touching all involve intricate series of chemical reactions and interactions in your body. With such an enormous range of topics, it is essential to know about chemistry at some level to understand the world around us.

In more formal terms chemistry is the study of matter and the changes it can undergo. Chemists sometimes refer to matter as ‘stuff’, and indeed so it is. Matter is anything that has mass and occupies space. Which is to say, anything you can touch or hold. Common usage might have us believe that ‘chemicals’ are just those substances in laboratories or something that is not a natural substance. Far from it, chemists believe that everything is made of chemicals.

Although there are countless types of matter all around us, this complexity is composed of various combinations of some 100 chemical elements. The names of some of these elements will be familiar to almost everyone. Elements such as hydrogen, chlorine, silver, and copper are part of our everyday knowledge. Far fewer people have heard of selenium or rubidium or hassium.

Nevertheless, all matter is composed of various combinations of these basic elements. The wonder of chemistry is that when these basic particles are combined, they make something new and unique. Consider the element sodium. It is a soft, silvery metal. It reacts violently with water, giving off hydrogen gas and enough heat to make the hydrogen explode. Nasty ‘stuff’. Also consider chlorine, a green gas when at room temperature. It is very caustic and choking, and is nasty enough that it was used as a horrible chemical gas weapon in the last century. So what kind of horrible mess is produced when sodium and chlorine are combined? Nothing more than sodium chloride, common table salt. Table salt does not explode in water or choke us; rather, it is a common additive for foods we eat everyday.

And so it is with chemistry, understanding the basic properties of matter and learning how to predict and explain how they change when they react to form new substances is what chemistry and chemists are all about.

Chemistry is not limited to beakers and laboratories. It is all around us, and the better we know chemistry, the better we know our world.

вторник, 5 марта 2024 г.

Physical chemistry

 Many chemical disciplines, such as those already discussed, focus on certain classes of materials that share common structural and chemical features. Other specialties may be centred not on a class of substances but rather on their interactions and transformations. The oldest of these fields is physical chemistry, which seeks to measure, correlate, and explain the quantitative aspects of chemical processes. The Anglo-Irish chemist Robert Boyle, for example, discovered in the 17th century that at room temperature the volume of a fixed quantity of gas decreases proportionally as the pressure on it increases. Thus, for a gas at constant temperature, the product of its volume V and pressure P equals a constant number—i.e., PV = constant. Such a simple arithmetic relationship is valid for nearly all gases at room temperature and at pressures equal to or less than one atmosphere. Subsequent work has shown that the relationship loses its validity at higher pressures, but more complicated expressions that more accurately match experimental results can be derived. The discovery and investigation of such chemical regularities, often called laws of nature, lie within the realm of physical chemistry. For much of the 18th century the source of mathematical regularity in chemical systems was assumed to be the continuum of forces and fields that surround the atoms making up chemical elements and compounds. Developments in the 20th century, however, have shown that chemical behaviour is best interpreted by a quantum mechanical model of atomic and molecular structure. The branch of physical chemistry that is largely devoted to this subject is theoretical chemistry. Theoretical chemists make extensive use of computers to help them solve complicated mathematical equations. Other branches of physical chemistry include chemical thermodynamics, which deals with the relationship between heat and other forms of chemical energy, and chemical kinetics, which seeks to measure and understand the rates of chemical reactions. Electrochemistry investigates the interrelationship of electric current and chemical change. The passage of an electric current through a chemical solution causes changes in the constituent substances that are often reversible—i.e., under different conditions the altered substances themselves will yield an electric current. Common batteries contain chemical substances that, when placed in contact with each other by closing an electrical circuit, will deliver current at a constant voltage until the substances are consumed. At present there is much interest in devices that can use the energy in sunlight to drive chemical reactions whose products are capable of storing the energy. The discovery of such devices would make possible the widespread utilization of solar energy.

There are many other disciplines within physical chemistry that are concerned more with the general properties of substances and the interactions among substances than with the substances themselves. Photochemistry is a specialty that investigates the interaction of light with matter. Chemical reactions initiated by the absorption of light can be very different from those that occur by other means. Vitamin D, for example, is formed in the human body when the steroid ergosterol absorbs solar radiation; ergosterol does not change to vitamin D in the dark.

A rapidly developing subdiscipline of physical chemistry is surface chemistry. It examines the properties of chemical surfaces, relying heavily on instruments that can provide a chemical profile of such surfaces. Whenever a solid is exposed to a liquid or a gas, a reaction occurs initially on the surface of the solid, and its properties can change dramatically as a result. Aluminum is a case in point: it is resistant to corrosion precisely because the surface of the pure metal reacts with oxygen to form a layer of aluminum oxide, which serves to protect the interior of the metal from further oxidation. Numerous reaction catalysts perform their function by providing a reactive surface on which substances can react.

вторник, 13 февраля 2024 г.

Polymer chemistry

 The simple substance ethylene is a gas composed of molecules with the formula CH2CH2. Under certain conditions, many ethylene molecules will join together to form a long chain called polyethylene, with the formula (CH2CH2)n, where n is a variable but large number. Polyethylene is a tough, durable solid material quite different from ethylene. It is an example of a polymer, which is a large molecule made up of many smaller molecules (monomers), usually joined together in a linear fashion. Many naturally occurring substances, including cellulose, starch, cotton, wool, rubber, leather, proteins, and DNA, are polymers. Polyethylene, nylon, and acrylics are examples of synthetic polymers. The study of such materials lies within the domain of polymer chemistry, a specialty that has flourished in the 20th century. The investigation of natural polymers overlaps considerably with biochemistry, but the synthesis of new polymers, the investigation of polymerization processes, and the characterization of the structure and properties of polymeric materials all pose unique problems for polymer chemists.

Polymer chemists have designed and synthesized polymers that vary in hardness, flexibility, softening temperature, solubility in water, and biodegradability. They have produced polymeric materials that are as strong as steel yet lighter and more resistant to corrosion. Oil, natural gas, and water pipelines are now routinely constructed of plastic pipe. In recent years, automakers have increased their use of plastic components to build lighter vehicles that consume less fuel. Other industries such as those involved in the manufacture of textiles, rubber, paper, and packaging materials are built upon polymer chemistry.

Besides producing new kinds of polymeric materials, researchers are concerned with developing special catalysts that are required by the large-scale industrial synthesis of commercial polymers. Without such catalysts, the polymerization process would be very slow in certain cases.

среда, 7 февраля 2024 г.

Biochemistry

 As understanding of inanimate chemistry grew during the 19th century, attempts to interpret the physiological processes of living organisms in terms of molecular structure and reactivity gave rise to the discipline of biochemistry. Biochemists employ the techniques and theories of chemistry to probe the molecular basis of life. An organism is investigated on the premise that its physiological processes are the consequence of many thousands of chemical reactions occurring in a highly integrated manner. Biochemists have established, among other things, the principles that underlie energy transfer in cells, the chemical structure of cell membranes, the coding and transmission of hereditary information, muscular and nerve function, and biosynthetic pathways. In fact, related biomolecules have been found to fulfill similar roles in organisms as different as bacteria and human beings. The study of biomolecules, however, presents many difficulties. Such molecules are often very large and exhibit great structural complexity; moreover, the chemical reactions they undergo are usually exceedingly fast. The separation of the two strands of DNA, for instance, occurs in one-millionth of a second. Such rapid rates of reaction are possible only through the intermediary action of biomolecules called enzymes. Enzymes are proteins that owe their remarkable rate-accelerating abilities to their three-dimensional chemical structure. Not surprisingly, biochemical discoveries have had a great impact on the understanding and treatment of disease. Many ailments due to inborn errors of metabolism have been traced to specific genetic defects. Other diseases result from disruptions in normal biochemical pathways.

Frequently, symptoms can be alleviated by drugs, and the discovery, mode of action, and degradation of therapeutic agents is another of the major areas of study in biochemistry. Bacterial infections can be treated with sulfonamides, penicillins, and tetracyclines, and research into viral infections has revealed the effectiveness of acyclovir against the herpes virus. There is much current interest in the details of carcinogenesis and cancer chemotherapy. It is known, for example, that cancer can result when cancer-causing molecules, or carcinogens as they are called, react with nucleic acids and proteins and interfere with their normal modes of action. Researchers have developed tests that can identify molecules likelyto be carcinogenic. The hope, of course, is that progress in the prevention and treatment of cancer will accelerate once the biochemical basis of the disease is more fully understood.

The molecular basis of biologic processes is an essential feature of the fast-growing disciplines of molecular biology and biotechnology. Chemistry has developed methods for rapidly and accurately determining the structure of proteins and DNA. In addition, efficient laboratory methods for the synthesis of genes are being devised. Ultimately, the correction of genetic diseases by replacement of defective genes with normal ones may become possible.